db.ini is for the emu to connect to your mysql, thus the username and pass are for loging into mysql.
loginserver.ini is your emu server config. You most likely have login.eqemu.net in your login.ini file instead of 127.0.0.1 that is required for use with minilogin.
It is hard to tell though since you didn't post any of your config files, or world and zone screen cut and pastes.
you also should post in the win32 support forum.
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